thus-synthesized,as-synthesized,pre-synthesized

英语翻译
The diamine in 3 was synthesized by diaza-Cope rearrangement reaction in a one-pot reaction (Scheme 1).Sequential addition of the two aldehydes to 4 results in efficient formation of the mixed diimine (6) followed by the rearrangement reaction to give 7.The two resonance-assisted hydrogen bonds in 7 drive the rearrangement
reaction to completion.We first synthesized a Co(III) complex of 7 using pyridine as a base.The crystal structure of the Co(III) complex (Figure 1) shows that the quinoline group coordinates to the metal,thereby forcing the nitrophenyl group to occupy the axial position as desired.Interestingly,a pyridine molecule is coordinated
to the cobalt complex and positioned almost parallel to the nitrophenyl group.The two groups are about 3.26-3.90 A apart.

英语翻译
We have recently synthesized Au nanocrystals by using a
MW-polyol method.13-15 When AuCl4- ions were reduced in
EG in the presence of the polymer surfactant PVP,triangular,
square,rhombic,and hexagonal nanoplates were preferentially
produced.When these nanostructures were used as seeds,Ag+
was reduced in order to synthesize Au core-Ag shell nano-
structures,denoted as Au@Ag.16Then,we have succeeded in
preparing some new Au@Ag nanocrystals having a good
correlation between the Au core and Ag shell.However,their
exact three-dimensional (3-D) crystal structures and the reason
why a good correlation arises in shape between the Au core
and Ag shell were not clarified in our previous communication.
Gold and silver have the same FCC crystal structures,and
the lattice constants of Au (0.0479 nm) and Ag (0.4086 nm)
are very similar.Therefore,it is known that both Au/Ag alloys
and various kinds of Au@Ag core-shell structures can be
prepared from Au/Ag reagents using various methods.17-27
Fortunately,Au@Ag core-shell structures with thin boundary
layers can easily be observed from transmission electron
microscopy (TEM) images,because Au cores and Ag shells
appear as clear black and blight contrasts,respectively.10,21
Therefore,we have found that there is a good correlation
between Au cores and Ag shells from TEM images of various
new Au@Ag core-shell structures.16
In this study,we have synthesized Au@Ag core-shell
nanostructures at different [AgNO3]/[HAuCl4] molar ratios.The
TEM images of Au@Ag crystals from different view angles,
selected area electron diffraction (SAED) patterns,and energy-
dispersive X-ray spectroscopy (EDS) analyses give new detailed
information on 3-D crystal structures and growth mechanisms
of each Au@Ag crystal in the presence of PVP.On the basis
of these data,we have succeeded in the clarification of general
growth mechanisms of FCC types of single crystals in the
presence of a polymer surfactant,which is difficult to obtain
from monometallic single crystals.

VHDL VGA中的综合问题
Signal colour cannot be synthesized, bad synchronous description. The description style you are using to describe a synchronous element (register, memory, etc.) is not supported in the current software release.
patter: process (x,y,mode,clk25,rst,colour)
variable count:integer range 0 to 25000000;
begin

case mode is
when "00" =>
if clk25'event and clk25 = '1' then
count:=count+1;
if count =25000000 then
colour
if clk25'event and clk25='1' then
if x =80 then
colour

英语翻译
是翻译这个：From D-glucosamine hydrochloride was synthesized,for the first time,three new optically active derivatives of D-glucosamine-pyrrole with the pyrrole group unsubstituted in the 2- and 5-positions.